| Title:  a-Hederin CAS Registry Number:  27013-91-8 Additional Names:  Helixin (the saponin) Molecular Formula:  C41H66O12 Molecular Weight:  750.96 Percent Composition:  C 65.57%, H 8.86%, O 25.57% Literature References:  Isoln from ivy leaves (Hedera helix L., Araliaceae):  van der Haar, Arch. Pharm. 250, 424 (1912); 251, 632, 650; idem, Biochem. Z. 76, 335 (1916); idem, Ber. 54, 3142 (1921).  Isoln and structure:  Tschesche et al., Z. Naturforsch. 20b, 708 (1965). Properties:  Precipitated from ethanol by addition of ether, mp 256-259°.  [a]D20 +14.5° (c = 0.92 in methanol). Melting point:  mp 256-259° Optical Rotation:  [a]D20 +14.5° (c = 0.92 in methanol)  |