Scopoline
Title: Scopoline
CAS Registry Number: 487-27-4
CAS Name: Hexahydro-4-methyl-2,5-methano-2H-furo[3,2-b]pyrrol-6-ol
Additional Names: 3b,7b-epoxy-1bH,5bH-tropan-6a-ol; 3a,6a-epoxy-7b-hydroxytropane
Trademarks: Oscine
Molecular Formula: C8H13NO2
Molecular Weight: 155.19
Percent Composition: C 61.91%, H 8.44%, N 9.03%, O 20.62%
Literature References: Decomposition product of scopolamine: Fodor, Kovács, J. Chem. Soc. 1953, 2341. Prepn from teloidine: Zeile, Heusner, Ber. 90, 2800, 2809 (1957); DE 1056617; DE 1062703 (1959 to Boehringer, Ing.). Structure: Fodor et al., J. Chem. Soc. 1955, 3504. Stereochemistry: Fodor, Tetrahedron 1, 86 (1957).
Properties: Crystals from petr ether, mp 107-109°. bp 248°. Sol in water, alcohol, acetone, ether.
Melting point: mp 107-109°
Boiling point: bp 248°
 
Derivative Type: Hydrochloride
Molecular Formula: C8H13NO2.HCl
Molecular Weight: 191.66
Percent Composition: C 50.13%, H 7.36%, N 7.31%, O 16.70%, Cl 18.50%
Properties: Crystals from ethanol, mp 255-257°.
Melting point: mp 255-257°
 
Derivative Type: Acetate
Molecular Formula: C10H15NO3
Molecular Weight: 197.23
Percent Composition: C 60.90%, H 7.67%, N 7.10%, O 24.34%
Properties: Crystals from petr ether, mp 56-57°.
Melting point: mp 56-57°

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