Title:  Uranium Tetrachloride 
CAS Registry Number:  10026-10-5 
Molecular Formula:  Cl4U 
Molecular Weight:  379.84 
Percent Composition:  Cl 37.33%, U 62.67% 
Line Formula:  UCl4 
Literature References:  Prepd from uranium(VI) oxide dihydrate and hexachloropropene:  Hermann, Suttle, Inorg. Synth. 5, 143 (1957). 
Properties:  Dark green octahedral crystals (tetragonal symmetry). Oxidizes in air and dec on contact with water.  Should be stored in sealed ampuls.  d425 4.725.  mp 590°, bp760 791°.  Heat of formation (solid) 250.9 kcal/mol at 0°.  Freely sol in water (dec).  Also sol in polar organic solvents.  Insol in nonpolar solvents such as hydrocarbons and ethyl ether. 
Melting point:  mp 590° 
Boiling point:  bp760 791° 
Density:  d425 4.725   |