sec-Octyl Bromide
Title: sec-Octyl Bromide
CAS Registry Number: 557-35-7
CAS Name: 2-Bromooctane
Molecular Formula: C8H17Br
Molecular Weight: 193.12
Percent Composition: C 49.75%, H 8.87%, Br 41.38%
Line Formula: CH3CHBr(CH2)5CH3
Literature References: Prepd by the action of PBr3 on sec-octyl alcohol: Hsueh, Marvel, J. Am. Chem. Soc. 50, 856 (1928); Reynolds, Adkins, ibid. 51, 279 (1929); Shriner, Young, ibid. 52, 3332 (1930); Ellis, Reid, ibid. 54, 1680 (1932); Coulson et al., J. Chem. Soc. 1965, 2364.
 
Derivative Type: dl-Form
Properties: d425 1.0878. bp14 72°. bp6 66°. bp3 61°. nD25 1.4442. Insol in water, miscible with alcohol, ether.
Boiling point: bp14 72°; bp6 66°; bp3 61°
Index of refraction: nD25 1.4442
Density: d425 1.0878
 
Derivative Type: l-Form
Properties: d425 1.0982. bp18 73°. bp14 71°. bp3 60°. nD25 1.4475. aD20 -44.91°.
Boiling point: bp18 73°; bp14 71°; bp3 60°
Optical Rotation: aD20 -44.91°
Index of refraction: nD25 1.4475
Density: d425 1.0982
 
Derivative Type: d-Form
Properties: d425 1.0982. bp18 77°. bp14 71°. bp3 60°. nD25 1.4475.
Boiling point: bp18 77°; bp14 71°; bp3 60°
Index of refraction: nD25 1.4475
Density: d425 1.0982

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